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                Lithium tri-sec-butylborohydride 三仲丁基硼氫化锂

                規格: 1.0 M solution in THF, SpcSeal
                CAS: 38721-52-7
                産品編号: H82325
                MDL: MFCD00011708
                品牌: INFI
                Chemical NameLithium tri-sec-butylborohydride
                Synonym lithium tri-sec-butylborohydride solution lithium,(beta-4)-borate(1-hydrotris(1-methylpropyl)- LITHIUM TRI-SEC-BUTYLHYDRIDOBORATE L-SELECTRIDE(R) 三仲丁基硼氫化锂 LITHIUM TRI-SEC-BUTYLBOROHYDRIDE LITHIUM TRI-SEC-BUTYLBOROHYDRIDE SOL. L-SELECTRIDE, 1.0M SOLUTION IN TETRAHYDR OFURAN Lithium tri-sec-butylborohydride solution LITHIUM TRI-S-BUTYLHYDROBORATE 1.0MsolutioninTHF Lithium tri-sec-butylborohydride, 1M solution in THF LITHIUM TRI-SEC-BUTYLBOROHYDRIDE SOL., 1 M IN THF A 800 ML L-Selectride® 溶液 三仲丁基硼氫化锂, 1.0M IN THF Borate(1-), hydrotris(1-methylpropyl)-, lithium, (T-4)- 三仲丁基硼化锂
                MDL NumberMFCD00011708
                PubChem Substance ID24855566
                Beilstein Registry Number4007327
                CAS Number38721-52-7
                Merck Number14,8427
                EC Number254-101-1
                Chemical Name Translation三仲丁基硼氫化锂
                LabNetwork Molecule IDLN01808673
                GHS Symbol
                WGK Germany3
                Precautionary statements
                • P222 Do not allow contact with air. 不要與空氣接觸。
                • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 遠離任何與水接觸的可能,因爲會劇烈反應可能産生閃火。
                • P422 Store contents under… 存儲目錄在…之下。
                • P231+P232
                • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 遠離熱源/火花/明火/熱的表面。——禁止吸煙。
                • P370+P378
                  Hazard statements
                  • H314 Causes severe skin burns and eye damage 導緻嚴重的皮膚灼傷和眼睛損傷
                  • H335 May cause respiratory irritation 可能導緻呼吸道刺激
                  • H351 Suspected of causing cancer 懷疑緻癌
                  • H260 In contact with water releases flammable gases which may ignite spontaneously 與水接觸時釋放可燃氣體,可自燃。
                  • H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
                  • H250 Catches fire spontaneously if exposed to air 暴露于空氣自發着火
                    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
                    Signal word
                    Safety Statements
                    • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不适時,立即求醫(可能時出示标簽);
                    • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸後,立即用大量水沖洗并征求醫生意見;
                    • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适當的防護服、手套和眼睛/面保護;
                    • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火時使用(指明具體的消防器材種類,如果用水增加危險,注明“禁止用水”
                    • S16 Keep away from sources of ignition - No smoking 遠離火源,禁止吸煙;
                      Packing GroupI
                      UN Number UN3394 UN 3394 4.2/PG 1
                      Risk Statements
                      • R11 Highly flammable 非常易燃
                      • R17 Spontaneously flammable in air 在空氣中能夠自燃
                      • R19 May form explosive peroxides 可能生成易爆的過氧化物質
                      • R37 Irritating to respiratory system 刺激呼吸道
                      • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水劇烈反應,釋放出高度可燃氣體
                      • R34 Causes burns 會導緻灼傷
                      • R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
                      • R40 Limited evidence of a carcinogenic effect 有限證據表明其緻癌作用
                        Storage condition Moisture Sensitive Flammables area
                        Hazard Codes F,C
                        Hazard Class4.3
                      • ⑴. 是一種有機硼烷,對濕氣和空氣比較敏感。
                      • ⑵. 用于有機合成中間體,被用作優秀的、溫和的和高度選擇性的還原試劑。具有較好的溶解度和較低價格的優勢,所以更廣泛地得到應用。它的分子中僅含有一個負氫離子,容易定量地控制試劑的用量;分子中有3個異丁基,自身具有較大的位阻,更容易在底物位阻小的區域發生選擇性反應。此外,三仲丁基硼氫化锂的還原能力明顯地受到反應溫度的影響。
                      • 在THF溶劑中,三仲丁基硼氫化锂與酮的還原反應可在低溫下進行。很多對反應條件敏感的官能團均不受到明顯的影響,例如:氰基、縮酮、縮醛、矽醚等。
                      • {ALD} Merck: 14,8427
                      • Beilstein: 4,IV,4361
                      • {ALD} Merck: 14,8427
                      • 38721-52-7 H82325 Lithium tri-sec-butylborohydride
三仲丁基硼氫化锂

                        化學屬性

                        Mol. FormulaC12H28BLi
                        Mol. Weight190.10
                        Density0.89
                        Flash Point-17°(1°F)
                        TSCAYes
                        Boiling Point203°C
                        Melting Point49°C
                        Solubilityreacts